Method for producing a high strength coated steel sheet having improved strength and ductility and obtained sheet

ABSTRACT

A coated steel sheet includes a chemical composition including in weight %: 0.13%≤C ≤0.22%; 1.2%≤Si≤1.8%; 1.8%≤Mn≤2.2%; 0.10%≤Mo≤0.20%; Nb≤0.05%; Al≤0.5%; Ti≤0.05%; and a remainder being Fe and unavoidable impurities. A structure of the steel sheet consists of, by volume fraction, 3% to 15% of residual austenite and 85% to 97% of martensite and bainite. The structure includes at least 65% of martensite and does not including ferrite. At least one face of the coated steel sheet includes a metallic coating. The steel sheet has a yield strength of at least 800 MPa, a tensile strength of at least 1180 MPa, a total elongation of at least 14% and a hole expansion ratio HER of at least 30%.

This is a Divisional of U.S. patent application Ser. No.15/322,722, filed Dec. 28, 2016 which is a National Phase of International Patent Application PCT/IB2015/055035, filed Jul. 3, 2015 claiming priority of International Patent Application PCT/IB2014/003249, filed Jul. 3, 2014, the entire disclosures of which are hereby incorporated by reference herein.

The present disclosure relates to a method for producing a high strength coated steel sheet having improved strength, ductility and formability and to the sheets obtained with the method.

BACKGROUND

To manufacture various equipments such as parts of body structural members and body panels for automotive vehicles, it is usual to use galvanized or galvannealed sheets made of DP (dual phase) steels or TRIP (transformation induced plasticity) steels.

For example, such steels which include a martensitic structure and/or some retained austenite and which contains about 0.2% of C, about 2% of Mn, about 1.7% of Si have a yield strength of about 750 MPa, a tensile strength of about 980 MPa, a total elongation of more than 8%. These sheets are produced on continuous annealing line by quenching from an annealing temperature higher than Ac₃ transformation point, down to an overaging temperature above Ms Transformation point and maintaining the sheet at the temperature for a given time. Then the sheet is galvanized or galvannealed.

SUMMARY

To reduce the weight of the automotive in order to improve their fuel efficiency in view of the global environmental conservation it is desirable to have sheets having improved yield and tensile strength. But such sheets must also have a good ductility and a good formability and more specifically a good stretch flangeability.

In this respect, it is desirable to have sheets having a yield strength YS of at least 800 MPa, a tensile strength TS of about 1180 MPa, a total elongation of at least 14% and a hole expansion ratio HER according to ISO standard 16630:2009 of more than 25%. It must be emphasized that, due to differences in the methods of measure, the values of hole expansion ration HER according to the ISO standard are very different and not comparable to the values of the hole expansion ratio λ, according to the JFS T 1001 (Japan Iron and Steel Federation standard).

Therefore, the purpose of the present disclosure is to provide such sheet and a method to produce it.

For this purpose, the present disclosure relates to a method for producing a high strength coated steel sheet having an improved strength and an improved formability, the sheet having a yield strength YS of at least 800 MPa, a tensile strength TS of at least 1180 MPa, a total elongation of at least 14% and a hole expansion ratio HER of at least 30%, by heat treating and coating a steel sheet whose chemical composition of the steel contains in weight %:

-   -   0.13%≤C≤0.22%     -   1.2%≤Si≤1.8%     -   1.8%≤Mn≤2.2%     -   0.10%≤Mo≤0.20%     -   Nb≤0.05%     -   A1≤0.5%         the remainder being Fe and unavoidable impurities. The heat         treatment and the coating comprise the following steps:     -   annealing the sheet at an annealing temperature TA higher than         Ac₃ but less than 1000° C. for a time of more than 30 s,     -   quenching the sheet by cooling it down to a quenching         temperature QT between 325° C. and 375° C., at a cooling speed         sufficient to obtain a structure consisting of of austenite and         at least 60% of martensite, the austenite content being such         that the final structure i.e. after treatment, coating and         cooling to the room temperature, can contain between 3% and 15%         of residual austenite and between 85% and 97% of the sum of         martensite and bainite, without ferrite     -   heating the sheet up to a partitioning temperature PT between         430° C. and 480° C. and maintaining the sheet at this         temperature for a partitioning time Pt between 10 s and 90 s,     -   hot dip coatings the sheet and,     -   cooling the sheet down to the room temperature.

Preferably, the quenching temperature QT is between 350° C. and 375° C.

Preferably, the partitioning temperature PT is between 435° C. and 465° C.

The chemical composition of the steel can satisfy at least one of the following conditions:

-   -   0.16%≤C≤0.20%     -   1.3%≤Si≤1.6%, and     -   1.9%≤Mn≤2.1%

The hot dip coating step may be a galvanizing step.

The hot dip coating step may be a galvannealing step with an alloying temperature TGA between 480° C. and 510° C. In this case, the partitioning time PT is preferably between 50 s and 70 s.

Preferably, after the sheet is quenched to the quenching temperature QT and before the sheet is heated to the partitioning temperature PT, the sheet is held at the quenching temperature QT for a holding time comprised between 2 s and 8 s, preferably between 3 s and 7 s.

The present disclosure, also, relates to a coated steel sheet whose chemical composition of the steel contains in weight %:

-   -   0.13%≤C≤0.22%     -   1.2%≤Si≤1.8%     -   1.8%≤Mn≤2.2%     -   0.10%≤Mo≤0.20%     -   Nb≤0.05%     -   Al≤0.5%     -   Ti≤0.05%         the remainder being Fe and unavoidable impurities. The structure         of the steel consists of 3% to 15% of residual austenite and 85%         to 97% of martensite and bainite, without ferrite. At least one         face of the sheet comprises a metallic coating. The sheet has a         yield strength of at least 800 MPa, a tensile strength of at         least 1180 MPa, a total elongation of at least 14% and a hole         expansion ratio HER of at least 30%.

Optionally the chemical composition of the steel can satisfy at least one of the following conditions:

-   -   0.16%≤C≤0.20%     -   1.3%≤Si≤1.6%, and     -   1.9%≤Mn≤2.1%

The at least one coated face is, for example, galvanized.

The at least one coated face is, for example, galvannealed.

BRIEF SUMMARY OF THE DRAWING

The present disclosure will now be described in details but without introducing limitations and illustrated by the FIGURE which is a micrograph of an example of the present disclosure.

DETAILED DESCRIPTION

According to the present disclosure, the sheet is obtained by hot rolling and optionally cold rolling of a semi product which chemical composition contains, in weight %:

-   -   0.13% to 0.22%, and preferably more than 0.16% preferably less         than 0.20% of carbon for ensuring a satisfactory strength and         improving the stability of the retained austenite which is         necessary to obtain a sufficient elongation. If carbon content         is too high, the hot rolled sheet is too hard to cold roll and         the weldability is insufficient.     -   1.2% to 1.8%, preferably more than 1.3% and less than 1.6% of         silicon in order to stabilize the austenite, to provide a solid         solution strengthening and to delay the formation of carbides         during overaging without formation of silicon oxides at the         surface of the sheet which is detrimental to coatability.     -   1.8% to 2.2% and preferably more than 1.9% and preferably less         than 2.1% of manganese to have a sufficient hardenability in         order to obtain a structure containing at least 65% of         martensite, tensile strength of more than 1150 MPa and to avoid         having segregation issues which are detrimental for the         ductility.     -   0.10% to 0.20% of molybdenium to increase the hardenability and         to stabilize the retained austenitic in order to strongly reduce         austenite decomposition during overaging.     -   up to 0.5% of aluminium which is usually added to liquid steel         for the purpose of deoxidation, preferably, the Al content is         limited to 0.05%. If the content of Al is above 0.5%, the         austenitizing temperature will be too high to be easily reached         and the steel will become industrially difficult to process.     -   Nb content and Ti content are limited to 0.05% each because         above such values numerous precipitates will form and         formability will decrease, making the 14% of total elongation         more difficult to reach.

The remainder being iron and residual elements resulting from the steelmaking. In this respect, Ni, Cr, Cu, V, B, S, P and N at least are considered as residual elements which are unavoidable impurities. Therefore, generally, their contents are less than 0.05% for Ni, 0.10% for Cr, 0.03 for Cu, 0.007% for V, 0.0010% for B, 0.005% for S, 0.02% for P and 0.010% for N.

The sheet is prepared by hot rolling and optionally cold rolling according to the methods known by those who are skilled in the art.

After rolling the sheets are pickled or cleaned then heat treated and hot dip coated.

The heat treatment which is made preferably on a combined continuous annealing and hot dip coating line comprises the steps of:

-   -   annealing the sheet at an annealing temperature TA higher than         the Ac₃ transformation point of the steel, and preferably higher         than Ac₃+15° C., in order to be sure that the structure is         completely austenitic, but less than 1000° C. in order not to         coarsen too much the austenitic grains. Generally, a temperature         higher than 865° C. is enough for the steel according to the         present disclosure. The sheet is maintained at the annealing         temperature i.e. maintained between TA−5° C. and TA+10° C., for         a time sufficient to homogenize the chemical composition.         Preferably, the time is of more than 30 s but does not need to         be of more than 300 s.     -   quenching the sheet by cooling down to a quenching temperature         QT lower than the Ms transformation point at a cooling rate         enough to avoid ferrite and bainite formation. The quenching         temperature is between 325° C. and 375° C. and preferably         between 350° C. and 375° C. in order to have, just after         quenching, a structure consisting of austenite and at least 60%         of martensite, the austenite content being such that the final         structure i.e. after treatment, coating and cooling to the room         temperature, can contain between 3% and 15% of residual         austenite and between 85 and 97% of the sum of martensite and         bainite, without ferrite. A cooling rate higher than 30° C./s is         enough,     -   reheating the sheet up to a partitioning temperature PT between         430° C. and 480° C. and preferably between 435° C. and 465° C.         For example, the partitioning temperature can be equal to the         temperature at which the sheet must be heated in order to be hot         dip coated, i.e. between 455° C. and 465° C. The reheating rate         can be high when the reheating is made by induction heater, but         that reheating rate had no apparent effect on the final         properties of the sheet. Preferably, between the quenching step         and the step of reheating the sheet to the partitioning         temperature PT, the sheet is held at the quenching temperature         for a holding time comprised between 2 s and 8 s, preferably         between 3 s and 7 s.     -   maintaining the sheet at the partitioning temperature PT for a         partitioning time Pt between 10 s and 90 s. Maintaining the         sheet at the partitioning temperature means that during         partitioning the temperature of the sheet remains between         PT−20° C. and PT+20° C.     -   optionally, adjusting the temperature of the sheet by cooling or         heating in order to be equal to the temperature at which the         sheet has to be heated in order to be hot dip coated.     -   hot dip coating the sheet, the hot dip coating being, for         example, galvanizing or galvannealing, but all type of metallic         hot dip coating is possible provided that the temperatures at         which the sheet is brought to during coating remains less than         650° C. . When the sheet is galvanized, it is done with the         usual conditions. When the sheet is galvannealed, the         temperature of alloying TGA must not be too high to obtain good         final mechanical properties. This temperature is preferably         between 500° and 580° C. Moreover, in this case, the         partitioning time is preferably between 50 s and 70 s.     -   generally, after coating, the sheet is processed according to         the known art. In particular the sheet is cooled to the room         temperature.

With such treatment, coated sheets having a yield strength YS of at least 800 MPa, a tensile strength of at least 1180 MPa, a total elongation of at least 14% and a hole expansion ratio HER according to the ISO standard 16630:2009 of at least 30% can be obtained.

As an example a sheet of 1.2 mm in thickness having the following composition:

C=0.18%, Si=1.5% Mn=2.0%, Nb=0.02%, Mo=0.15%, the remainder being Fe and impurities, was manufactured by hot and cold rolling. The theoretical Ms transformation point of this steel is 386° C. and the Ac₃ point is 849° C.

Samples of the sheet were heat treated by annealing, quenching and partitioning then galvanized or galvannealed, and the mechanical properties were measured.

The conditions of treatment and the obtained properties are reported at table I for the samples that were galvanized and at table II for the samples that were galvannealed.

TABLE I TA QT PT Pt YS TS UE TE HER Sample ° C. ° C. ° C. s MPa MPa % % % 1 900 300 460 60 1116 1207 7 12 2 900 350 460 30 952 1215 9 14 3 900 350 460 60 926 1199 8 14 31 4 900 350 460 90 909 1207 9 14 5 900 400 460 60 709 1187 10 15 6 900 460 460 60 685 1178 9 14

TABLE II TA QT PT Pt TGA YS TS UE TE HER Sample ° C. ° C. ° C. s ° C. MPa MPa % % % 7 900 350 460 60 500 838 1185 9 14 34 8 900 350 460 60 520 854 1215 9 12 9 900 350 460 60 520 869 1167 8 12 -20 s- 10 900 350 460 60 570 898 1106 7 13

In these tables, TA is the annealing temperature, QT the quenching temperature, PT the partitioning temperature, Pt the maintaining time at the partitioning temperature, TGA the temperature of alloying for the sheets that were galvannealed, YS the yield strength, TS the tensile strength, UE the uniform elongation, TE the total elongation and HER the hole expansion ratio measured according to the ISO 16630:2009 standard.

For example 9, “520-20” (TGA) means that the steel has been at the GA temperature of 520° C. for 20 seconds, in the other examples (7,8 and 10) once the GA temperature is reached, then the temperature decreases slowly before the final cooling.

Examples 1 to 4 show that with a quenching temperature equal or less than 350° C., a partitioning at a temperature of 460° C. with a partitioning time from 30 s to 90 s galvanized sheets have a yield strength higher than 800 MPa, a tensile strength higher than 1180 MPa, a total elongation of more than or equal to 12% and a hole expansion ratio measured according to ISO standard 16630: 2009 higher than 30%.

Examples for which the quenching temperature is higher than Ms are comparative examples and/or according to the prior art. The structure contains ferrite or bainite and austenite and the yield strength is significantly less than 800 MPa.

The examples 7 to 10 show that, when the sheet is galvannealed, the temperature of alloying has to be as low as possible to obtain a total elongation of 14% and a hole expansion ratio HER of more than 30%. Example 7, a micrograph of which is shown at the figure, contains 7% of retained austenite and 96% of the sum of martensite and bainite.

The conditions of treatment and the obtained properties are reported at table I for the samples that were galvanized and at table II for the samples that were galvannealed. 

What is claimed is:
 1. A coated steel sheet comprising: a chemical composition of the steel including in weight %: 13%≤C≤0.22%; 2%≤Si≤1.8%; 8%≤Mn≤2.2% 0.10%≤Mo≤0.20%; Nb≤0.05%; Al≤0.5%; and Ti≤0.05%; a remainder being Fe and unavoidable impurities; a structure consisting of, by volume fraction, 3% to 15% of residual austenite and 85% to 97% of martensite and bainite, the structure including at least 65% of martensite, the structure not including ferrite; at least one face of the coated steel sheet including a metallic coating; and a yield strength of at least 800 MPa, a tensile strength of at least 1180 MPa, a total elongation of at least 14% and a hole expansion ratio HER of at least 30%.
 2. The coated steel sheet according to claim 1, wherein the chemical composition of the steel satisfies at least one of the following conditions: 16%≤C≤0.20%; 3%≤Si≤1.6%; and 1.9%≤Mn≤2.1%.
 3. The coated steel sheet according to claim 1, wherein the at least one face including a metallic coating is galvanized.
 4. The coated steel sheet according to claim 1, wherein the at least one face including a metallic coating is galvannealed.
 5. The coated steel sheet according to claim 1, wherein the chemical composition of the steel satisfies 0.02%≤Nb≤0.05%. 